Yes, the European Union has activated the Temporary Protection Directive. This means that persons from Ukraine will be offered temporary residence in Åland. You can apply for this at Ålands polismyndighet
You have the right to work in Åland as soon as your register your application with the police. The police will provide you with a printed certificate proving your right to work (you no longer need to wait for the temporary residence permit).
If you need support in finding work in Åland, register with us at AMS, Ålands arbetsmarknads- och studieservicemyndighet (Åland Public Employment Service).